F. Javier García de Abajo Institut de Ciències Fotòniques (ICFO)

Plasmons in noble metals, such as silver and gold, have been used to color glass since ancient times. In recent years, plasmonics has made its way through to become a key component in the field of optical devices essential in the miniaturization of optoelectronic devices to the nanoscale. It is known that plasmonic interactions between electrons and photons change significantly in materials when one or more of the dimensions of the metallic object are reduced down to the nanometer scale. The advent of graphene and other two-dimensional crystals has helped display appealing properties of plasmons such as a large electrical tunability. However, the plasmons generated in these materials are too broad or exist at too low frequencies, in a range that is well below the expected near-infrared regime needed for most optical devices.

In a recent study in ACS Nano (cover image in July 2019), ICFO researchers in collaboration with the University of the Basque Country report on the fabrication and the excellent plasmonic and electronic properties of wafer scale atomically thin crystalline silver films composed of only a few atomic layers.

Through a two-step process of fabrication and under ultrahigh-vacuum conditions, the team of researchers was able grow high-quality flat silver films on silicon wafers, with a thickness as small as seven atomic monolayers. The film quality was high enough to resolve quantum electronic states through angle-resolved photoemission. To excite and probe plasmons in this films, they first carved nanoribbon arrays, and then shined near-infrared light.

The results of this study prove that atom-thin crystalline silver films are capable of supporting highquality narrow plasmons in the near infrared. In addition, this study has proven that such material could be the perfect alternative to highly-doped graphene, which, despite its amazing properties, has so far reached the mid-infrared, far from the technologically attractive near-infrared region. The observation of these spectrally sharp and strongly confined plasmons in atomically thin silver holds great potential for electro-optical modulation and optical sensing applications.


Abd El-Fattah ZM, Mkhitaryan V, Brede J, Fernández L, Li C, Guo Q, Ghosh A, Rodríguez Echarri A, Naveh D, Xia F, Ortega JE & García de Abajo FJ 2019, ‘Plasmonics in atomically thin crystalline silver films’. ACS Nano 13, 7771-7779.