Arjan W. Kleij

Arjan W. Kleij

Institut Català d'Investigació Química

Experimental Sciences & Mathematics

Arjan obtained his MSc (with honors) and PhD (cum laude) from the University of Utrecht (NL). In 2002 he moved to Spain as a NWO TALENT fellow with Javier de Mendoza, followed by another postdoc at the University of Amsterdam (NL) working with Joost Reek. He also held various scientific positions in the industry at Avantium and Hexion. In 2006, he returned to Spain as a junior ICREA fellow and ICIQ Group Leader, and was promoted to ICREA Professor in 2011. He is a member of several advisory and editorial boards (Green. Chem., Adv. Synth. Catal., ChemCatChem, Journal of CO2 Utilization, ACS Sust. Chem. Engin., ChemSusChem), was chair of the EUGSC-4 conference in 2019 and is co-chair of the SHOCS symposium in 2025, and associate editor for Organic Chemistry Frontiers (RSC). Citations >18600, h-index of around 72. He received the 2020 RSEQ Excellence, 2023 SCQ Excellence and the 2023 European Sustainable Chemistry Awards, and became a FRSC in 2021.

Research interests

The research of my group focuses on the valorization and recycling of small molecules (including CO2) into value-added chemicals and polymeric materials. We design new and more sustainable catalytic methods and processes to apply them in selective organic synthesis processes. We employ homogeneous catalysis approaches based on metal complexes and/or organocatalysts, and investigate important process features such as catalyst recycling, energy/material efficiencies, atom-efficiency and overall selectivity/reactivity profiles. In all these endeavors, we wish to develop novel types of stereoselective and enantioselective transformations including those focusing on the preparation of compounds featuring challenging quaternary stereocenters. Our generic view on chemistry is to pursue and increase circularity as to sustain a healthy and global perspective for future generations to come.

Selected publications

- Brandolese A, Lamparelli DH, Grimaldi I, Impemba S, Baglioni P, Kleij AW 2024, 'Access to Functionalized Polycarbonates Derived from Fatty Acid Esters via Catalytic ROCOP and Their Potential in Gel Formulations', Macromolecules, 57, 3816-3823.
- Zeng Q, Nirwan Y, Benet-Buchholz J & Kleij AW 2024, 'An Expedient Radical Approach for the Decarboxylative Synthesis of Stereodefined All-Carbon Tetrasubstituted Olefins', Angewandte Chemie International Edition, 63, e202403651.
- Pijper B, Saavedra L, Lanzi M, Alonso M, Fontana A, Serrano M, Gómez JE, Kleij AW, Alcázar J, Cañellas S 2024, 'Addressing Reproducibility Challenges in High-Throughput Photochemistry', JACS Au, 4, 2585−2595.
- Delgado A, Orlando P, Lanzi M, Benet-Buchholz J, Passarella D & Kleij AW 2024, 'Cu-Catalyzed Asymmetric Synthesis of γ-Amino Alcohols Featuring Tertiary Carbon Stereocenters', Organic Letters, 26, 7596-7600.
- Gao FY, Ghorai D, Benet-Buchholz J & Kleij AW 2024, 'Pd-Catalyzed Allylic Substitution Using Nucleophilic Amines: Access to Functionalized Mono- and Bis-N-Allyl Synthons', Advanced Synthesis & Catalysis, 366, 4709-4714.

Selected research activities

2024 Secretary of the Green Chemistry section (GEQV) of the Spanish Chemical Society (RSEQ)
2024 Plenary lecture at the 12th Workshop on Fats and Oils as Renewable Feedstock in Dortmund/GER
2024 Keynote lecture at the SISOC XIV in Torino/ITA
2024 Plenary lecture at the 13ª Trobada de Joves Investigadors dels Països Catalans, Secció Jove de la Societat Catalana de Química, in Tarragona/ESP
2024 Member of the selection committee for the SCQ awards
2024 Appointed member of the scientific committee of the 2025 ICCDU in Lisbon/POR
2024 EP24382310 “Procedure for the functionalization of cellulose, functionalized cellulose thus obtained and use thereof"